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Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

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Abstract

A 2D porous MOF, {[Cu(1,2,3-btc)(bpe)(H2O)]·H2O}n (1), has been synthesized using a mixed linker system. The structural determination showed non-coordinated carboxylate groups decorating the pore surface. The desolvated MOF (1a) with pendant carboxylate groups was used as a template for the stabilization of Pd nps (2–3 nm) and the resulting composite Pd(0)@1a showed efficient catalytic activity for the Suzuki–Miyaura C–C coupling reaction.

Graphical abstract: Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

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Publication details

The article was received on 03 Dec 2018, accepted on 26 Mar 2019 and first published on 26 Mar 2019


Article type: Communication
DOI: 10.1039/C8DT04766A
Dalton Trans., 2019, Advance Article

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    Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

    S. A. Adalikwu, V. S. Mothika, A. Hazra and T. K. Maji, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04766A

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