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Issue 18, 2019
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Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

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Abstract

We report the first molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand. By employing several spectroscopic methods we are able to pinpoint the pentaphosphine environment and evaluate the activation of the dinitrogen ligand. Furthermore, we conduct protonation experiments and obtain spectroscopic evidence for the formation of a hydrazido-species.

Graphical abstract: Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

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Article information


Submitted
30 Nov 2018
Accepted
29 Jan 2019
First published
31 Jan 2019

Dalton Trans., 2019,48, 6019-6025
Article type
Paper

Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

T. Weyrich, J. Krahmer, T. A. Engesser, C. Näther and F. Tuczek, Dalton Trans., 2019, 48, 6019
DOI: 10.1039/C8DT04738C

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