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Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

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Abstract

We report the first molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand. By employing several spectroscopic methods we are able to pinpoint the pentaphosphine environment and evaluate the activation of the dinitrogen ligand. Furthermore, we conduct protonation experiments and obtain spectroscopic evidence for the formation of a hydrazido-species.

Graphical abstract: Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

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Publication details

The article was received on 30 Nov 2018, accepted on 29 Jan 2019 and first published on 31 Jan 2019


Article type: Paper
DOI: 10.1039/C8DT04738C
Citation: Dalton Trans., 2019, Advance Article

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    Molybdenum dinitrogen complex supported by a cyclohexane-based triphosphine ligand and dmpm

    T. Weyrich, J. Krahmer, T. A. Engesser, C. Näther and F. Tuczek, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04738C

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