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Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)] via reaction with CS2

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Abstract

Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4] affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)] (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)], the first DNIC featuring both linear/bent NO ligands and Fe 3dz2-to-HCS2 π* backbonding interaction.

Graphical abstract: Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]− via reaction with CS2

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Publication details

The article was received on 29 Nov 2018, accepted on 04 Jan 2019 and first published on 05 Jan 2019


Article type: Communication
DOI: 10.1039/C8DT04714F
Citation: Dalton Trans., 2019, Advance Article

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    Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)] into [(NO)2Fe(η3-HCS2)] via reaction with CS2

    H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04714F

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