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Issue 3, 2019
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Recent developments in the chemistry of metal oxopolyazides

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Abstract

The recent acomplished syntheses of novel metal oxopolyazides VO(N3)3, NbO(N3)3, NbO(N3)3·2CH3CN, MoO(N3)3, MoO(N3)3·2CH3CN, WO(N3)4, WO(N3)4·CH3CN, MoO2(N3)2, MoO2(N3)2·2CH3CN, WO2(N3)2, WO2(N3)2·2CH3CN and UO2(N3)2·CH3CN by the author is reviewed. The conversion of the compounds into 2,2′-bipyridine donor adducts and oxaazido metallates is discribed. The properties and X-ray crystal structures of the metal oxopolyazides are compared and discussed.

Graphical abstract: Recent developments in the chemistry of metal oxopolyazides

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Publication details

The article was received on 24 Oct 2018, accepted on 12 Dec 2018 and first published on 12 Dec 2018


Article type: Frontier
DOI: 10.1039/C8DT04258F
Dalton Trans., 2019,48, 806-813

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    Recent developments in the chemistry of metal oxopolyazides

    R. Haiges, Dalton Trans., 2019, 48, 806
    DOI: 10.1039/C8DT04258F

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