Issue 3, 2019
From the journal:

Dalton Transactions

Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands†

Patrick Steinhoff,a   Melanie Paul,a   Julian P. Schroersa  and  Michael E. Tauchert ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, D-52074 Aachen, Germany
E-mail: Michael.Tauchert@ac.rwth-aachen.de

Abstract

A series of zero-valent palladium complexes featuring diphosphinometal ligands is reported. The metalloligand in the PMP-type framework (M = LiI, CuI, ZnII) acts as a weak to medium acceptor ligand for palladium. A Pd0→ZnII bond was observed in the solid state and further confirmed by NBO analysis. The heterobimetallic Pd/Zn complex 2-Zn displayed excellent activity in chemoselective CO2 hydrosilylation producing silyl formate (TOF1/2 = 3000 h−1).

Graphical abstract: Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8DT03777A
Article type
Paper
Submitted
18 Sep 2018
Accepted
14 Dec 2018
First published
14 Dec 2018

Dalton Trans., 2019,48, 1017-1022

Permissions

Request permissions

Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands

P. Steinhoff, M. Paul, J. P. Schroers and M. E. Tauchert, Dalton Trans., 2019, 48, 1017 DOI: 10.1039/C8DT03777A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements