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Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system

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Abstract

The compound (NBu4)4[ZnII{ReIVCl4(μ-ox)}3] (1) [NBu4+ = tetra-n-butylammonium cation and ox2− = oxalate dianion] is the first example of an oxalato-bridged ZnII system coordinated to a 5d metal ion that exhibits slow relaxation of magnetisation.

Graphical abstract: Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system

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Publication details

The article was received on 14 Sep 2018, accepted on 18 Oct 2018 and first published on 19 Oct 2018


Article type: Communication
DOI: 10.1039/C8DT03728K
Citation: Dalton Trans., 2019, Advance Article
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    Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIReIV3] system

    A. Sanchis-Perucho, C. Rojas-Dotti, N. Moliner and J. Martínez-Lillo, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT03728K

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