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Issue 22, 2019
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Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

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Abstract

Manganese(I) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 °C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

Graphical abstract: Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

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Publication details

The article was received on 28 Aug 2019, accepted on 13 Oct 2019 and first published on 17 Oct 2019


Article type: Paper
DOI: 10.1039/C9CY01738K
Catal. Sci. Technol., 2019,9, 6370-6378
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    Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(I) complexes bearing triazole ligands

    O. Martínez-Ferraté, B. Chatterjee, C. Werlé and W. Leitner, Catal. Sci. Technol., 2019, 9, 6370
    DOI: 10.1039/C9CY01738K

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