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The role of speciation of Ni2+ and its interaction with support for selectivity and stability in conversion of ethylene to propene

Abstract

Different kinds of Ni2+ species or phases ranging in their speciation from isolated sites to nanostructured NiO and Ni silicate or Ni aluminate were prepared on the surface of silica, alumina, and silica-alumina by grafting, incipient wetness impregnation and template-ion exchange methods. The nature of surface NiOx species was elucidated on the basis of characterisation by UV-vis spectroscopy, XRD, FTIR spectroscopy of adsorbed carbon monoxide and temperature-programmed reduction with hydrogen. Acidity of both the supports and the catalysts was studied by FTIR spectroscopy of adsorbed pyridine. Amount and nature of coke formed on the catalysts during the reaction was characterised by temperature-programmed oxidation. The highest propene selectivity of 40% at ethylene conversion of 50% and the lowest selectivity to coke were obtained over the catalyst possessing highly dispersed or even isolated NiOx sites connected to Al3+ in the silica-alumina support. The propene selectivity over this catalyst is higher than that achieved over the state-of-the-art Ni/AlMCM-41 catalyst prepared by complicated template-ion exchange procedure. Ni2+ supported on silica, even when prepared by grafting, suffers from low propene selectivity due to severe coke production directly from ethylene. Thus NiOx bound to Si is not well suited for ethylene reaction to propene. Ni2+ grafted on alumina is less active and selective due to formation of surface Ni aluminate.

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Supplementary files

Publication details

The article was received on 11 Apr 2019, accepted on 09 May 2019 and first published on 09 May 2019


Article type: Paper
DOI: 10.1039/C9CY00696F
Catal. Sci. Technol., 2019, Accepted Manuscript

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    The role of speciation of Ni2+ and its interaction with support for selectivity and stability in conversion of ethylene to propene

    M. Stoyanova, U. Bentrup, H. Atia, E. V. Kondratenko, D. Linke and U. Rodemerck, Catal. Sci. Technol., 2019, Accepted Manuscript , DOI: 10.1039/C9CY00696F

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