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Issue 10, 2019
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(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

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Abstract

Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions.

Graphical abstract: (Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

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Article information


Submitted
10 Apr 2019
Accepted
23 Apr 2019
First published
25 Apr 2019

Catal. Sci. Technol., 2019,9, 2421-2425
Article type
Communication

(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

M. F. Pinto, M. Olivares, Á. Vivancos, G. Guisado-Barrios, M. Albrecht and B. Royo, Catal. Sci. Technol., 2019, 9, 2421
DOI: 10.1039/C9CY00685K

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