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Issue 16, 2019
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Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

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Abstract

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form important N-heterocycles. If suitable nitrene precursors are employed, organometallic complexes are able to catalyze the C–H amination under mild conditions. In the past years, Fe catalysis has emerged as a vigorously developing new (old) discipline. The present review highlights the most important developments in this field through a systematic differentiation between open-shell (radical) and closed-shell (non-radical) mechanisms.

Graphical abstract: Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

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Publication details

The article was received on 09 Apr 2019, accepted on 03 Jul 2019 and first published on 03 Jul 2019


Article type: Minireview
DOI: 10.1039/C9CY00675C
Catal. Sci. Technol., 2019,9, 4188-4197

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    Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

    B. Plietker and A. Röske, Catal. Sci. Technol., 2019, 9, 4188
    DOI: 10.1039/C9CY00675C

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