Doping homogeneity in co-doped materials investigated at different length scales

Abstract

Doping homogeneity is important for the properties of co-doped phosphors, as it can affect the energy transfer between sensitizer and activator ions. In a case study we apply different methods, that is scanning electron microscopy (SEM) combined with energy dispersive X-ray spectroscopy (EDX) mapping, SEM combined with cathodoluminescence (CL) and solid-state nuclear magnetic resonance (NMR), to study the doping homogeneity of the host system monazite LaPO₄ doped with two different lanthanide ions on different length scales. A new criterion for doping heterogeneity in co-doped systems is developed, which is based on the NMR visibility function, which for this purpose is extended to doping with two or more paramagnetic dopants. A deviation from this function is indicative of doping heterogeneity on the length-scale of the blind-spheres of the paramagnetic dopants. A discussion of the advantages and disadvantages of the different methods is presented. The combined approach allows to study doping homogeneity from the nm to the μm scale.