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Issue 43, 2019
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Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

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Abstract

Step-scan Fourier-transform infrared spectroscopy was used to monitor the photochemical reactions following the 266 nm-photolysis of aqueous ferrioxalate solutions on microsecond-to-millisecond time scales. Together with most recent observations from ultrafast infrared spectroscopy the reported results finally disclose the full molecular-level mechanism of a photochemical system that is widely known as the Hatchard–Parker actinometer.

Graphical abstract: Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

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Article information


Submitted
23 Sep 2019
Accepted
23 Oct 2019
First published
23 Oct 2019

Phys. Chem. Chem. Phys., 2019,21, 23803-23807
Article type
Communication

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

F. H. Pilz, J. Lindner and P. Vöhringer, Phys. Chem. Chem. Phys., 2019, 21, 23803
DOI: 10.1039/C9CP05233J

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