Jump to main content
Jump to site search


MoS2 coated CoS2 nanocomposites as counter electrodes in Pt-free dye-sensitized solar cells

Author affiliations

Abstract

Expensive Pt counter electrodes remain an obstacle for the commercialization of dye-sensitized solar cells (DSSCs). Therefore, research focusing on low-cost alternative counter electrode materials has been considered important for their commercialization. Here, the fabrication of dye-sensitized solar cells has been performed utilizing CoS2 and MoS2 coated CoS2 nanocomposite materials as the counter electrode, which are synthesized via a hydrothermal route involving low-cost precursor materials. The experimental results obtained from XRD, XPS, EDX, SEM, TEM, and Raman etc. have confirmed the successful formation of CoS2 and MoS2 coated CoS2 nanocomposites. The electrochemical characterization of these materials is performed, which suggests that the electrocatalytic activity towards the liquid iodine electrolyte of these materials is as good as that of the conventional Pt counter electrodes. So, dye-sensitized solar cell devices are fabricated by interpolating a (cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)) dye-loaded TiO2 photoanode and CoS2, MoS2 coated CoS2 and Pt counter electrodes using iodine/iodide as a liquid electrolyte. The devices fabricated with CoS2 counter electrodes have shown an open circuit voltage of 790 mV, a short circuit current of 11.9 mA cm−2, a fill factor of 0.54, and a power conversion efficiency of 6%. On the other hand, the device based on a Pt counter electrode has shown an open circuit voltage of 773 mV, a short circuit current of 13.4 mA cm−2, a fill factor of 0.54, and a power conversion efficiency of 6.6%. In addition, MoS2 coated with a CoS2 counter electrode has shown the best performance with an open circuit voltage of 763 mV, a short circuit current of 20.1 mA cm−2, a fill factor of 0.42, and a power conversion efficiency of 7.6%.

Graphical abstract: MoS2 coated CoS2 nanocomposites as counter electrodes in Pt-free dye-sensitized solar cells

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Aug 2019, accepted on 22 Oct 2019 and first published on 22 Oct 2019


Article type: Paper
DOI: 10.1039/C9CP04592A
Phys. Chem. Chem. Phys., 2019, Advance Article

  •   Request permissions

    MoS2 coated CoS2 nanocomposites as counter electrodes in Pt-free dye-sensitized solar cells

    V. Subbiah, G. Landi, J. J. Wu and S. Anandan, Phys. Chem. Chem. Phys., 2019, Advance Article , DOI: 10.1039/C9CP04592A

Search articles by author

Spotlight

Advertisements