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Issue 42, 2019
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Control defeasance by anti-alignment in the excited state

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Abstract

We predict anti-alignment dynamics in the excited state of H2+ or related homonuclear dimers in the presence of a strong field. This effect is a general indirect outcome of the strong transition dipole and large polarizabilities typically used to control or to induce alignment in the ground state. In the excited state, however, the polarizabilities have the opposite sign compared to those in the ground state, generating a torque that aligns the molecule perpendicular to the field, deeming any laser-control strategy impossible.

Graphical abstract: Control defeasance by anti-alignment in the excited state

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Article information


Submitted
09 Aug 2019
Accepted
07 Oct 2019
First published
07 Oct 2019

Phys. Chem. Chem. Phys., 2019,21, 23620-23625
Article type
Paper

Control defeasance by anti-alignment in the excited state

B. Y. Chang, S. Shin, J. González-Vázquez, F. Martín, V. S. Malinovsky and I. R. Sola, Phys. Chem. Chem. Phys., 2019, 21, 23620
DOI: 10.1039/C9CP04427B

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