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Valuable structure-size relationships for tadpole-shaped single-chain nanoparticles with long and short flexible tails unveiled

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Abstract

Tadpole-shaped single-chain nanoparticles (TSCNPs) are useful soft building blocks for nanotechnology composed of a flexible polymer chain tethered to an intramolecularly folded single-chain nanoparticle. We disclose herein valuable structure-size relationships for a priori TSCNP design depending on tail length, which are validated by experimental data from multiple TSCNP systems, allowing, for the first time, the prediction of TSCNP size before synthesis.

Graphical abstract: Valuable structure-size relationships for tadpole-shaped single-chain nanoparticles with long and short flexible tails unveiled

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Publication details

The article was received on 08 Mar 2019, accepted on 10 May 2019 and first published on 10 May 2019


Article type: Communication
DOI: 10.1039/C9CP01318K
Phys. Chem. Chem. Phys., 2019, Advance Article

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    Valuable structure-size relationships for tadpole-shaped single-chain nanoparticles with long and short flexible tails unveiled

    I. Asenjo-Sanz, E. Verde-Sesto and J. A. Pomposo, Phys. Chem. Chem. Phys., 2019, Advance Article , DOI: 10.1039/C9CP01318K

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