Direct conversion of carbon nanofibers into diamond nanofibers using nanosecond pulsed laser annealing

Abstract

Here, we show the direct conversion of carbon nanofibers (CNFs) into diamond nanofibers (DNFs) by irradiating CNFs with an ArF nanosecond laser at room temperature and atmospheric pressure. The nanosecond laser pulses melt the tips of CNFs into a highly undercooled state, and their subsequent quenching results in the formation of DNFs. This formation of DNFs is dependent on the degree of undercooling which is controlled by nanosecond laser energy density and one-dimensional heat flow characteristics in CNFs. The conversion process starts at the top and extends with the number of pulses. Therefore, our highly non-equilibrium nanosecond laser processing opens a new avenue for the synthesis of exciting pure and doped diamond structures at ambient temperatures and pressures for a variety of applications.