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Issue 16, 2019
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Control of post-growth processes for the selection of metallo-tetraphenylporphyrin nanowires

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Abstract

Controlling self-organization of small organic molecules in nanostructures with a desired shape and size is one of the main challenges in organic nanoelectronics. Here, a strategy for selectively growing uniaxially aligned nanowires of meso-tetraphenyl porphyrin–Zn(II) (ZnTPP) is presented. ZnTPP is deposited on an organic single crystal, namely potassium hydrogen phthalate, by organic molecular beam epitaxy. The films typically display a rather rich surface morphology, characterized by the presence of nanowires and other nm-sized aggregates, most of them unstable over time. Post-growth processes occurring via quasi-Ostwald ripening both in air and in vacuum demonstrate an aging protocol in vacuum as a tool for the selection of ZnTPP nanowires, whose morphology and uniaxial orientation are demonstrated to be led by organic epitaxy. The ability of growing ZnTPP nanowires with a unique crystal structure and precise orientation gives the chance to observe the intrinsic optical anisotropy of the triclinic polymorph of ZnTPP crystal and establishes the role of intermolecular interactions, providing new perspectives in the study of the intrinsic physical properties of ZnTPP crystals.

Graphical abstract: Control of post-growth processes for the selection of metallo-tetraphenylporphyrin nanowires

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Publication details

The article was received on 19 Dec 2018, accepted on 26 Mar 2019 and first published on 27 Mar 2019


Article type: Paper
DOI: 10.1039/C8CP07747A
Citation: Phys. Chem. Chem. Phys., 2019,21, 8482-8488

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    Control of post-growth processes for the selection of metallo-tetraphenylporphyrin nanowires

    L. Raimondo, S. Trabattoni and A. Sassella, Phys. Chem. Chem. Phys., 2019, 21, 8482
    DOI: 10.1039/C8CP07747A

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