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Issue 3, 2019
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Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

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Abstract

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)2(pyz)3 has an intrachain coupling J = 13.7(1) K (Image ID:c8cp07160h-t1.gif) and exhibits a state of long-range magnetic order below TN = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J′/J| = 3.3 × 10−3, demonstrating a high degree of isolation for the Cu chains.

Graphical abstract: Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

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Publication details

The article was received on 20 Nov 2018, accepted on 14 Dec 2018 and first published on 14 Dec 2018


Article type: Communication
DOI: 10.1039/C8CP07160H
Phys. Chem. Chem. Phys., 2019,21, 1014-1018

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    Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3

    B. M. Huddart, J. Brambleby, T. Lancaster, P. A. Goddard, F. Xiao, S. J. Blundell, F. L. Pratt, J. Singleton, P. Macchi, R. Scatena, A. M. Barton and J. L. Manson, Phys. Chem. Chem. Phys., 2019, 21, 1014
    DOI: 10.1039/C8CP07160H

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