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Issue 3, 2019
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Radiative cooling of cationic carbon clusters, CN+, N = 8, 10, 13–16

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Abstract

The radiative cooling of highly excited carbon cluster cations of sizes N = 8, 10, 13–16 has been studied in an electrostatic storage ring. The cooling rate constants vary with cluster size from a maximum at N = 8 of 2.6 × 104 s−1 and a minimum at N = 13 of 4.4 × 103 s−1. The high rates indicate that photon emission takes place from electronically excited ions, providing a strong stabilizing cooling of the molecules.

Graphical abstract: Radiative cooling of cationic carbon clusters, CN+, N = 8, 10, 13–16

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Publication details

The article was received on 12 Oct 2018, accepted on 19 Dec 2018 and first published on 21 Dec 2018


Article type: Paper
DOI: 10.1039/C8CP06368K
Citation: Phys. Chem. Chem. Phys., 2019,21, 1587-1596
  • Open access: Creative Commons BY-NC license
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    Radiative cooling of cationic carbon clusters, CN+, N = 8, 10, 13–16

    F.-Q. Chen, N. Kono, R. Suzuki, T. Furukawa, H. Tanuma, P. Ferrari, T. Azuma, J. Matsumoto, H. Shiromaru, V. Zhaunerchyk and K. Hansen, Phys. Chem. Chem. Phys., 2019, 21, 1587
    DOI: 10.1039/C8CP06368K

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