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Probing ultrafast dynamics during and after passing through conical intersections

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Abstract

Time-resolved photoelectron spectroscopy using vacuum-UV probe pulses enables observing ultrafast dynamics during and after passing through conical intersections (CIs). The ring-puckering CI plays a prominent role following the ππ* photoexcitation of furan. More than 90% of the excited molecules safely return to the original ground state, while the remaining 10% transforms into isomers after passing through the puckering CI.

Graphical abstract: Probing ultrafast dynamics during and after passing through conical intersections

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Publication details

The article was received on 13 Jul 2018, accepted on 24 Sep 2018 and first published on 24 Sep 2018


Article type: Communication
DOI: 10.1039/C8CP04426K
Citation: Phys. Chem. Chem. Phys., 2019, Advance Article
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    Probing ultrafast dynamics during and after passing through conical intersections

    S. Adachi, T. Schatteburg, A. Humeniuk, R. Mitrić and T. Suzuki, Phys. Chem. Chem. Phys., 2019, Advance Article , DOI: 10.1039/C8CP04426K

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