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Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

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Abstract

The reaction of a doubly bis(2-pyridyl)pyrazolate (bpypz) bridged dinuclear cationic copper(II) complex with 7,7′,8,8′-tetracyano-p-quinodimethanido radicals (TCNQ˙) afforded a tetranuclear complex, [Cu4(μ-bpypz)4(μ-TCNQ)2](TCNQ)2 (1), which self-assembles into a three-dimensional supramolecular coordination architecture via complementary weak coordination bonding and π–π stacking interactions.

Graphical abstract: Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

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Publication details

The article was received on 07 Oct 2019, accepted on 30 Oct 2019 and first published on 31 Oct 2019


Article type: Communication
DOI: 10.1039/C9CE01580A
CrystEngComm, 2019, Advance Article

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    Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

    R. Ishikawa, S. Ueno, H. Iguchi, B. K. Breedlove, M. Yamashita and S. Kawata, CrystEngComm, 2019, Advance Article , DOI: 10.1039/C9CE01580A

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