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Issue 2, 2020
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Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

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Abstract

The reaction of a doubly bis(2-pyridyl)pyrazolate (bpypz) bridged dinuclear cationic copper(II) complex with 7,7′,8,8′-tetracyano-p-quinodimethanido radicals (TCNQ˙) afforded a tetranuclear complex, [Cu4(μ-bpypz)4(μ-TCNQ)2](TCNQ)2 (1), which self-assembles into a three-dimensional supramolecular coordination architecture via complementary weak coordination bonding and π–π stacking interactions.

Graphical abstract: Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

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Article information


Submitted
07 Oct 2019
Accepted
30 Oct 2019
First published
31 Oct 2019

CrystEngComm, 2020,22, 159-163
Article type
Communication

Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

R. Ishikawa, S. Ueno, H. Iguchi, B. K. Breedlove, M. Yamashita and S. Kawata, CrystEngComm, 2020, 22, 159
DOI: 10.1039/C9CE01580A

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