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Issue 44, 2019
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Unprecedented five-fold interpenetrated donor–acceptor hybrid heterostructure induced by anion–π interactions

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Abstract

The combination of hexacyanoferrate anions with protonated N,N′-dipyridyl-naphthalene diimide tectons resulted in a novel cuboid 3-D H-bonded anion-coordinated framework. Induced by anion–π interactions, such a unique framework is further catenated into an unprecedented five-fold interpenetrated D–A hybrid heterostructure with 1-D hexacyanoferrate polyanions and naphthalene diimide aggregates as electron donors and acceptors, respectively. The photophysical and photochemical properties have also been discussed.

Graphical abstract: Unprecedented five-fold interpenetrated donor–acceptor hybrid heterostructure induced by anion–π interactions

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Publication details

The article was received on 08 Sep 2019, accepted on 10 Oct 2019 and first published on 11 Oct 2019


Article type: Communication
DOI: 10.1039/C9CE01416K
CrystEngComm, 2019,21, 6688-6692

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    Unprecedented five-fold interpenetrated donor–acceptor hybrid heterostructure induced by anion–π interactions

    M. You, M. Li, Y. Liu, H. Li and M. Lin, CrystEngComm, 2019, 21, 6688
    DOI: 10.1039/C9CE01416K

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