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Preparation of CL-20/TFAZ cocrystals under aqueous conditions: balancing high performance and low sensitivity

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Abstract

Cocrystals of hexanitrohexaazaisowurtzitane (CL-20) and 7H-trifurazano[3,4-b:3′,4′-f:3′′,4′′-d]azepine (TFAZ) in a 1 : 1 molar ratio were prepared by both slow evaporation and self-assembly methods. Structure determination showed that they belong to the monoclinic system (space group P21) with a crystal density of 1.932 g cm−3. The intermolecular hydrogen bonds and N–O⋯NO2 type interactions are demonstrated as the predominant driving forces in the cocrystal formation. Furthermore, the cocrystals were successfully synthesized by a self-assembly method using only water as a solvent under mild conditions and the product yield was up to 92.3%. The two types of cocrystals were fully characterized by powder X-ray diffraction, infrared spectroscopy and scanning electron microscopy. Moreover, the thermal behavior, sensitivity, and calculated detonation performance of the cocrystals were evaluated. The cocrystals exhibit good thermal stability (Td = 242.8 °C), low impact sensitivity (H50 = 42 cm) and friction sensitivity (Pf = 38%), high crystal density, and high calculated detonation velocity (9103 m s−1). This work opens up a new perspective in the environment-friendly preparation of energetic cocrystals on a large-scale, as well as providing potential low-sensitivity and high-energy explosives.

Graphical abstract: Preparation of CL-20/TFAZ cocrystals under aqueous conditions: balancing high performance and low sensitivity

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Publication details

The article was received on 21 Jul 2019, accepted on 16 Oct 2019 and first published on 18 Oct 2019


Article type: Paper
DOI: 10.1039/C9CE01221D
CrystEngComm, 2019, Advance Article

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    Preparation of CL-20/TFAZ cocrystals under aqueous conditions: balancing high performance and low sensitivity

    N. Liu, B. Duan, X. Lu, Q. Zhang, M. Xu, H. Mo and B. Wang, CrystEngComm, 2019, Advance Article , DOI: 10.1039/C9CE01221D

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