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A zinc(II) metal−organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

Abstract

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]•(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity based on experimental and simulation calculation results. Furthermore, the selectivities of CO2/CH4 and CO2/N2 are predicted by IAST to be 41.19 and 46.21 at 298 K and 100 KPa, respectively. The superior performance suggests 1 is a promising candidate for CO2 separation.

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Supplementary files

Publication details

The article was accepted on 13 May 2019 and first published on 14 May 2019


Article type: Paper
DOI: 10.1039/C9CE00513G
CrystEngComm, 2019, Accepted Manuscript

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    A zinc(II) metal−organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

    D. Sheng, Y. Zhang, Y. Han, G. Xu, Y. Hu, Q. Song, X. Liu, D. Shan and A. Cheng, CrystEngComm, 2019, Accepted Manuscript , DOI: 10.1039/C9CE00513G

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