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Enhanced proton conductivity of a MOF-808 framework through anchoring organic acids to the zirconium clusters by post-synthetic modification

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Abstract

The modified MOF-808 frameworks MOF-808-EDTA/OX show better proton conduction behaviours than the original framework. A high proton conductivity (1.94 × 10−4 S cm−1) of MOF-808-OX can be obtained at 30 °C and 98% relative humidity. This is the first example where proton conductivity is tuned by modifying the metal cluster-based nodes via a post-synthetic modification method.

Graphical abstract: Enhanced proton conductivity of a MOF-808 framework through anchoring organic acids to the zirconium clusters by post-synthetic modification

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Publication details

The article was received on 07 Mar 2019, accepted on 28 Apr 2019 and first published on 29 Apr 2019


Article type: Communication
DOI: 10.1039/C9CE00328B
CrystEngComm, 2019, Advance Article

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    Enhanced proton conductivity of a MOF-808 framework through anchoring organic acids to the zirconium clusters by post-synthetic modification

    X. Meng, H. Wang, L. Wang, Y. Zou and Z. Zhou, CrystEngComm, 2019, Advance Article , DOI: 10.1039/C9CE00328B

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