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Solvent-Induced SC-SC Transformation within the ZnII-Triazole System: A Promising MnO4- Selective Luminescent Probe

Abstract

A series of coordination polymers based on the ligand tris(4-(1H-1,2,4-triazol-1-yl)phenyl)amine (TTPA) have been developed. Amongst these, complexation with Zn2+ results in a 1D ladder complex. The solvent-induced SC-SC transformation within the Zn2+-triazole system has resulted in a unique solvate, generating {[Zn(TTPA)(NO3)2]·2CHBr3}n (4a). Compound 4a was tested for both cation and anion capture of important industrial pollutants. The Luminescence properties of 4a indicated that it could be considered as a new triazole based selective luminescent probe for both Pb2+ and MnO4-.

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Supplementary files

Publication details

The article was received on 05 Mar 2019, accepted on 09 May 2019 and first published on 13 May 2019


Article type: Communication
DOI: 10.1039/C9CE00312F
CrystEngComm, 2019, Accepted Manuscript

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    Solvent-Induced SC-SC Transformation within the ZnII-Triazole System: A Promising MnO4- Selective Luminescent Probe

    L. Cheng, Y. Wang, D. Yang, Y. Zhang, Y. Gao and G. S. Day, CrystEngComm, 2019, Accepted Manuscript , DOI: 10.1039/C9CE00312F

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