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Influence of interpenetration on the flexibility of MUV-2

Abstract

The crystal structure of an interpenetrated tetrathiafulvalene(TTF)-based metal-organic framework (MOF) is reported. This MOF, denoted MUV-2-i, is the interpenetrated analogue of the hierarchical and flexible MUV-2. Interestingly, the large flexibility exhibited by MUV-2 upon polar solvent adsorption is considerably reduced in the interpenetrated form which can be explained by short S···S interactions between adjacent TTF-based ligands ensuring more rigidity to the framework. In addition, porosity of MUV-2-i significantly decreased in comparison to MUV-2 as shown by the reduced free volume in the crystal structure.

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Publication details

The article was received on 18 Feb 2019, accepted on 06 Apr 2019 and first published on 08 Apr 2019


Article type: Paper
DOI: 10.1039/C9CE00233B
Citation: CrystEngComm, 2019, Accepted Manuscript

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    Influence of interpenetration on the flexibility of MUV-2

    M. Vicent-Morales, I. Vitorica-Yrzebal, M. Souto and G. Minguez Espallargas, CrystEngComm, 2019, Accepted Manuscript , DOI: 10.1039/C9CE00233B

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