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Infinite and discrete halogen bonded assemblies based upon 1,2-bis(iodoethynyl)benzene

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Abstract

The ability to form both infinite and discrete co-crystals based upon 1,2-bis(iodoethynyl)benzene as a halogen bond donor has been realized. The various co-crystals are held together by I⋯N halogen bonds from the donor to either a symmetrical bipyridine or an unsymmetrical monopyridine-based acceptor producing a one-dimensional wave-like polymer or discrete assembly, respectively.

Graphical abstract: Infinite and discrete halogen bonded assemblies based upon 1,2-bis(iodoethynyl)benzene

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Publication details

The article was received on 21 Nov 2018, accepted on 07 Jan 2019 and first published on 08 Jan 2019


Article type: Paper
DOI: 10.1039/C8CE01984C
Citation: CrystEngComm, 2019, Advance Article
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    Infinite and discrete halogen bonded assemblies based upon 1,2-bis(iodoethynyl)benzene

    E. Bosch, S. J. Kruse and R. H. Groeneman, CrystEngComm, 2019, Advance Article , DOI: 10.1039/C8CE01984C

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