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N-heterocyclic silylene stabilized monocordinated copper(i)–arene cationic complexes and their application in click chemistry

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Abstract

Herein for the first time we report monocoordinated cationic Cu(I) complexes with unsymmetrical arenes (toluene and m-xylene) [LCu(η3-C7H8)]+[SbF6] and [{LCu(η2-Me2C6H4)}]+[SbF6] [L = {PhC(NtBu)2SiN(SiMe3)2}], [IPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)], their reactivity and catalytic applications in CuAAC reactions (12 examples). The bonding analysis was performed in both silylene and carbene complexes using the EDA-NOCV method at the BP86/TZ2P level of theory.

Graphical abstract: N-heterocyclic silylene stabilized monocordinated copper(i)–arene cationic complexes and their application in click chemistry

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Publication details

The article was received on 22 Nov 2019, accepted on 28 Nov 2019 and first published on 28 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC09115G
Chem. Commun., 2020, Advance Article

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    N-heterocyclic silylene stabilized monocordinated copper(I)–arene cationic complexes and their application in click chemistry

    N. Parvin, J. Hossain, A. George, P. Parameswaran and S. Khan, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09115G

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