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A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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Abstract

An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

Graphical abstract: A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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Publication details

The article was received on 21 Nov 2019, accepted on 26 Nov 2019 and first published on 26 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC09063K
Chem. Commun., 2020, Advance Article

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    A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

    X. Sun, Z. Tang, Z. Yao and J. Tao, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09063K

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