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Exploiting kinetics for assembly of multicomponent nanoparticle networks with programmable control of heterogeneity

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Abstract

Kinetic control of metal chalcogenide nanoparticle oxidative assembly is realized by varying the redox potential of the chalcogenide, structure (wurtzite vs. zinc blende), and ligand chain length. This knowledge is exploited to form two-component (ZnS + CdSe) hybrid aerogels with minimal heterobonding (phase-segregated) or maximal heterobonding (intimately mixed).

Graphical abstract: Exploiting kinetics for assembly of multicomponent nanoparticle networks with programmable control of heterogeneity

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Publication details

The article was received on 20 Nov 2019, accepted on 04 Dec 2019 and first published on 04 Dec 2019


Article type: Communication
DOI: 10.1039/C9CC09027D
Chem. Commun., 2020, Advance Article

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    Exploiting kinetics for assembly of multicomponent nanoparticle networks with programmable control of heterogeneity

    J. L. Davis, K. L. Silva and S. L. Brock, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09027D

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