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A Simple Cobalt–Based Catalyst System for the Controlled Dehydropolymerisation of H3B·NMeH2 on the Gram-Scale

Abstract

A simple Co(II)–based amine–borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.

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Publication details

The article was received on 13 Nov 2019, accepted on 02 Dec 2019 and first published on 03 Dec 2019


Article type: Communication
DOI: 10.1039/C9CC08864D
Chem. Commun., 2019, Accepted Manuscript

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    A Simple Cobalt–Based Catalyst System for the Controlled Dehydropolymerisation of H3B·NMeH2 on the Gram-Scale

    T. M. Boyd, K. A. Andrea, K. Baston, A. Johnson, D. E. Ryan and A. Weller, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC08864D

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