The first divalent-metal iodate-phosphate, Pb2(IO3)(PO4), has been prepared via the strategy of introducing (IO3)− into phosphate. The structure features a unique 3D network where [Pb(IO3)]+ ∞ and [Pb(PO4)]− ∞ layers are alternatively interconnected. The birefringence of Pb2(IO3)(PO4) is greatly increaed to 0.060 at 1064 nm.
The article was received on 08 Nov 2019, accepted on 04 Dec 2019 and first published on 04 Dec 2019
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