A new iodate-phosphate Pb2(IO3)(PO4) achieving great improvement in birefringence activated by (IO3)− groups

Xiao-Han Zhang; Bing-Ping Yang; Jin Chen; Chun-Li Hu; Zhi Fang; Zujian Wang; Jiang-Gao Mao

doi:10.1039/C9CC08739G

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A new iodate-phosphate Pb₂(IO₃)(PO₄) achieving great improvement in birefringence activated by (IO₃)⁻ groups†

Xiao-Han Zhang,^ab Bing-Ping Yang,

*^a Jin Chen,

^a Chun-Li Hu,^a Zhi Fang,

^a Zujian Wang^a and Jiang-Gao Mao

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: ybp@fjirsm.ac.cn, mjg@fjirsm.ac.cn

^b College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, P. R. China

Abstract

The first divalent-metal iodate-phosphate, Pb₂(IO₃)(PO₄), has been prepared via the strategy of introducing (IO₃)⁻ into phosphate. The structure features a unique 3D network where [Pb(IO₃)]_∞⁺ and [Pb(PO₄)]_∞⁻ layers are alternatively interconnected. The birefringence of Pb₂(IO₃)(PO₄) is greatly increased to 0.060 at 1064 nm.

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Article information

DOI: https://doi.org/10.1039/C9CC08739G
Article type: Communication
Submitted: 08 Nov 2019
Accepted: 04 Dec 2019
First published: 04 Dec 2019

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Chem. Commun., 2020,56, 635-638

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A new iodate-phosphate Pb₂(IO₃)(PO₄) achieving great improvement in birefringence activated by (IO₃)⁻ groups

X. Zhang, B. Yang, J. Chen, C. Hu, Z. Fang, Z. Wang and J. Mao, Chem. Commun., 2020, 56, 635 DOI: 10.1039/C9CC08739G

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