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A New Iodate-Phosphate Pb2(IO3)(PO4) Achieving Great Improvement in Birefringence Activated by (IO3)− Groups

Abstract

The first divalent-metal iodate-phosphate, Pb2(IO3)(PO4), has been prepared via the strategy of introducing (IO3)− into phosphate. The structure features a unique 3D network where [Pb(IO3)]+ ∞ and [Pb(PO4)]− ∞ layers are alternatively interconnected. The birefringence of Pb2(IO3)(PO4) is greatly increaed to 0.060 at 1064 nm.

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Publication details

The article was received on 08 Nov 2019, accepted on 04 Dec 2019 and first published on 04 Dec 2019


Article type: Communication
DOI: 10.1039/C9CC08739G
Chem. Commun., 2019, Accepted Manuscript

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    A New Iodate-Phosphate Pb2(IO3)(PO4) Achieving Great Improvement in Birefringence Activated by (IO3)− Groups

    B. Yang, X. Zhang, J. Chen, C. Hu, Z. Fang, Z. Wang and J. Mao, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC08739G

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