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Issue 99, 2019
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Extremely twisted and bent pyrene-fused N-heterocyclic germylenes

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Abstract

The first examples of pyrene-fused Janus-type N-heterocyclic germylenes (NHGe) are reported. Remarkably, the pyrene linker and the germanium containing rings are extremely twisted, with “twist angles” up to 64°. Coordination of a Lewis base modifies the twisting of pyrene to an overall bent core (141° bend angle).

Graphical abstract: Extremely twisted and bent pyrene-fused N-heterocyclic germylenes

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Submitted
07 Nov 2019
Accepted
12 Nov 2019
First published
13 Nov 2019

Chem. Commun., 2019,55, 14954-14957
Article type
Communication
Author version available

Extremely twisted and bent pyrene-fused N-heterocyclic germylenes

K. E. Krantz, S. L. Weisflog, W. Yang, D. A. Dickie, N. C. Frey, C. E. Webster and R. J. Gilliard, Chem. Commun., 2019, 55, 14954
DOI: 10.1039/C9CC08703F

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