Issue 3, 2020

Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

Abstract

A pure-inorganic framework based on {P4MoV4MoVI2} clusters with rich phosphate groups has been synthesized. It underwent a single crystal to single crystal conversion in air to form a new framework with changes both in the metal valent state and coordination environment. The new framework exhibits an ultra-high proton conductivity of 1.33 × 10−2 S cm−1 at 95 °C and 98% relative humidity and excellent stability.

Graphical abstract: Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

Supplementary files

Article information

Article type
Communication
Submitted
07 Nov 2019
Accepted
29 Nov 2019
First published
30 Nov 2019

Chem. Commun., 2020,56, 391-394

Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

S. Zhang, Y. Lu, X. Sun, Z. Li, T. Dang, Z. Zhang, H. Tian and S. Liu, Chem. Commun., 2020, 56, 391 DOI: 10.1039/C9CC08696J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements