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Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

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Abstract

A pure-inorganic framework based on {P4MoV4MoVI2} clusters with rich phosphate groups has been synthesized. It underwent a single crystal to single crystal conversion in air to form a new framework with changes both in the metal valent state and coordination environment. The new framework exhibits an ultra-high proton conductivity of 1.33 × 10−2 S cm−1 at 95 °C and 98% relative humidity and excellent stability.

Graphical abstract: Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

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Publication details

The article was received on 07 Nov 2019, accepted on 29 Nov 2019 and first published on 30 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08696J
Chem. Commun., 2020, Advance Article

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    Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

    S. Zhang, Y. Lu, X. Sun, Z. Li, T. Dang, Z. Zhang, H. Tian and S. Liu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08696J

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