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Issue 98, 2019
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A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

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Abstract

A highly symmetric, dicationic tetranuclear calcium hydride cluster with an adamantoid [Ca4H6]2+ core stabilized by the NNN macrocycle Me3TACN (1,4,7-trimethyl-1,4,7-triazacyclononane) was prepared. DFT calculations indicate delocalized bonding within the [Ca4H6]2+ fragment with d-orbital contribution.

Graphical abstract: A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

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Publication details

The article was received on 01 Nov 2019, accepted on 19 Nov 2019 and first published on 19 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08540H
Chem. Commun., 2019,55, 14837-14839

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    A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

    D. Schuhknecht, T. P. Spaniol, I. Douair, L. Maron and J. Okuda, Chem. Commun., 2019, 55, 14837
    DOI: 10.1039/C9CC08540H

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