Jump to main content
Jump to site search

Issue 98, 2019
Previous Article Next Article

One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

Author affiliations

Abstract

Herein, we report a new method for the one-pot syntheses of sulfonyl fluorides. Addition of an alkyl, aryl, or heteroaryl Grignard to a solution of sulfuryl fluoride at ambient temperature affords the desired sulfonyl fluorides in 18–78% yield. Furthermore, this method is applicable for in situ sequential reactions, whereby the Grignard reagent can be converted to the corresponding diarylsulfone, sulfonate ester, or sulfonamide in a one-pot process.

Graphical abstract: One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

Back to tab navigation

Supplementary files

Publication details

The article was received on 30 Oct 2019, accepted on 15 Nov 2019 and first published on 15 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08487H
Chem. Commun., 2019,55, 14753-14756

  •   Request permissions

    One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

    C. Lee, N. D. Ball and G. M. Sammis, Chem. Commun., 2019, 55, 14753
    DOI: 10.1039/C9CC08487H

Search articles by author

Spotlight

Advertisements