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A new type of composite MOFs based on high-valent Sb(v)-based units and cuprous-halide clusters

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Abstract

An unusual high-valent Sb(V)-based unit [SbL2] (L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) was developed for the first time to combine with various cuprous-halide clusters for the construction of a brand-new class of heterometallic MOFs. This work not only promotes the limited development of Sb-based MOFs, but also provides a practical strategy for developing new types of composite materials.

Graphical abstract: A new type of composite MOFs based on high-valent Sb(v)-based units and cuprous-halide clusters

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Publication details

The article was received on 29 Oct 2019, accepted on 21 Nov 2019 and first published on 22 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08443F
Chem. Commun., 2019, Advance Article

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    A new type of composite MOFs based on high-valent Sb(V)-based units and cuprous-halide clusters

    L. Lin, Z. Li, J. Liu, Y. Sun, X. Li and S. Zheng, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC08443F

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