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Issue 1, 2020
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Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

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Abstract

The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C–I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.

Graphical abstract: Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

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Article information


Submitted
26 Oct 2019
Accepted
25 Nov 2019
First published
26 Nov 2019

Chem. Commun., 2020,56, 82-85
Article type
Communication

Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

W. Fan, J. Li, W. Lv, L. Yang, Q. Li and H. Wang, Chem. Commun., 2020, 56, 82
DOI: 10.1039/C9CC08386C

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