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Kinetic investigation of chemical process in single-molecule junction

Abstract

We report on the kinetic investigation for the breakdown of single-molecule junctions. Currents through the junctions was measured as a function of time to elucidate their lifetimes. The analysis of the lifetimes revealed that the breakdown reaction obeys first-order reaction kinetics, and the rate constants determined from the analysis was found to reflect the stability of the junctions.

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Publication details

The article was accepted on 15 Nov 2019 and first published on 18 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08383A
Chem. Commun., 2019, Accepted Manuscript

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    Kinetic investigation of chemical process in single-molecule junction

    Y. Hasegawa, T. Harashima, Y. Jono, T. Seki, M. Kiguchi and T. Nishino, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC08383A

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