Jump to main content
Jump to site search


Convenient Synthesis of Phosphinecarboxamide and Phosphinecarbothioamide by Hydrophosphination of Isocyanate and Isothiocyanate

Abstract

Reactions of isocyanates with primary and secondary phosphines without solvent at room temperature afforded the corresponding phosphinecarboxamide (RN(H)COPRꞌ2) in excellent yiled. This reaction system is applicable for isothiocyanate. The compounds newly obtained were fully characterized using multielement NMR spectroscopy. In addition, the molecular structure of Cl(CH2)2N(H)COPPh2 was studied by single-crystal X-ray diffraction.

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Oct 2019, accepted on 29 Nov 2019 and first published on 29 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08329D
Chem. Commun., 2019, Accepted Manuscript

  •   Request permissions

    Convenient Synthesis of Phosphinecarboxamide and Phosphinecarbothioamide by Hydrophosphination of Isocyanate and Isothiocyanate

    M. Itazaki, T. Matsutani, T. Nochida, T. Moriuchi and H. Nakazawa, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC08329D

Search articles by author

Spotlight

Advertisements