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Reversible pyrrole-based proton storage/release in ruthenium(ii) complexes

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Abstract

Newly designed ruthenium(II) complexes are reported which contain a pyridylpyrrole ligand featuring fast-responsive and reversible proton storage/release on the pyrrole group. The protonated pyrrolium acts as an acidic initiator and is capable of triggering the polymerization of 2,2-dimethyloxirane.

Graphical abstract: Reversible pyrrole-based proton storage/release in ruthenium(ii) complexes

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Publication details

The article was received on 22 Oct 2019, accepted on 05 Nov 2019 and first published on 06 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08288C
Chem. Commun., 2019, Advance Article

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    Reversible pyrrole-based proton storage/release in ruthenium(II) complexes

    Z. Zhang, P. He, S. Kang, C. Liu and X. Yi, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC08288C

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