Issue 96, 2019

Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

Abstract

Herein we report the development of diffusion ordered NMR spectroscopy (DOSY) for its use to characterize metal complexes containing paramagnetic first row transition metal elements. This technique is capable of assessing the purity and speciation of paramagnetic complexes, and also provides a convenient method to provide qualitative and sometimes quantitative molecular weight data.

Graphical abstract: Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

Supplementary files

Article information

Article type
Communication
Submitted
20 Oct 2019
Accepted
07 Nov 2019
First published
08 Nov 2019

Chem. Commun., 2019,55, 14426-14429

Author version available

Adding diffusion ordered NMR spectroscopy (DOSY) to the arsenal for characterizing paramagnetic complexes

M. P. Crockett, H. Zhang, C. M. Thomas and J. A. Byers, Chem. Commun., 2019, 55, 14426 DOI: 10.1039/C9CC08229H

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