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Issue 98, 2019
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A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

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Abstract

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Graphical abstract: A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

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Publication details

The article was received on 15 Oct 2019, accepted on 15 Nov 2019 and first published on 15 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08094E
Chem. Commun., 2019,55, 14781-14784

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    A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

    N. Huang, X. Zhang, Y. Xu, P. Liao and X. Chen, Chem. Commun., 2019, 55, 14781
    DOI: 10.1039/C9CC08094E

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