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Abstract | Cited by

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Graphical abstract: A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

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