Ning-Yu Huang, Xue-Wen Zhang, Yu-Zhi Xu, Pei-Qin Liao and Xiao-Ming Chen
Chem. Commun., 2019,55, 14781-14784
DOI:
10.1039/C9CC08094E,
Communication
The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.