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Base-free Ni-catalyzed Suzuki-type cross-coupling reactions of epoxides with boronic acids

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Abstract

A Ni-catalyzed Suzuki-type cross-coupling of boronic acids with epoxides without an exogenous base and with broad substrate scope has been developed. The product selectivity of styrenyl epoxides is different from that of previous work. This methodology uses readily available starting materials to access a range of substituted alcohols, which are valuable feedstock chemicals.

Graphical abstract: Base-free Ni-catalyzed Suzuki-type cross-coupling reactions of epoxides with boronic acids

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Publication details

The article was received on 15 Oct 2019, accepted on 24 Nov 2019 and first published on 26 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08079A
Chem. Commun., 2020, Advance Article

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    Base-free Ni-catalyzed Suzuki-type cross-coupling reactions of epoxides with boronic acids

    X. Lu, L. Yan, J. Li, J. Li, H. Zhou, R. Jiang, C. Liu, R. Lu and R. Hu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08079A

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