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Issue 92, 2019
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Construction of seven- and eight-membered carbocycles by Lewis acid catalyzed C(sp3)–H bond functionalization

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Abstract

We achieved a concise construction of seven- and eight-membered carbocycles via Lewis acid catalyzed C(sp3)–H bond functionalization. In these reactions, a quite rare [1,6 (or 7)]-hydride shift/cyclization process proceeded smoothly to afford seven- and eight-membered carbocycles with good chemical yields starting from substrates with high conformational freedom.

Graphical abstract: Construction of seven- and eight-membered carbocycles by Lewis acid catalyzed C(sp3)–H bond functionalization

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Publication details

The article was received on 15 Oct 2019, accepted on 25 Oct 2019 and first published on 25 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC08074K
Chem. Commun., 2019,55, 13856-13859

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    Construction of seven- and eight-membered carbocycles by Lewis acid catalyzed C(sp3)–H bond functionalization

    Y. Otawa and K. Mori, Chem. Commun., 2019, 55, 13856
    DOI: 10.1039/C9CC08074K

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